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Beilstein J. Org. Chem. 2022, 18, 1026–1031, doi:10.3762/bjoc.18.103
Graphical Abstract
Scheme 1: From vinyl acetates to α-azidoketones.
Scheme 2: Substrate scope. Reaction conditions: α-arylvinyl acetate (0.5 mmol), TMSN3 (1.0 mmol), n-Bu4NPF6 (...
Scheme 3: Derivatization of α-azidoketone 2.
Scheme 4: Proposed mechanism.
Beilstein J. Org. Chem. 2014, 10, 1261–1266, doi:10.3762/bjoc.10.126
Scheme 1: Transition metal-catalyzed allylic substitution reactions with monosubstituted allyl substrates.
Figure 1: Representative ligands developed for the regio- and enantioselective Pd-catalyzed allylic alkylatio...
Scheme 2: Preparation of 1-[bis(trifluoromethyl)phosphine]-1’-oxazolinylferrocene ligands. Reagents and condi...
Scheme 3: Comparison of the effect of ligands in the reaction.
Figure 2: Preliminary explanation of the regioselectivity.